1.1.49 — "a genitive [ending, in a rule,] when connected [with what follows], denotes 'in place of.'" This one परिभाषा is what makes every replacement rule in the grammar parse: without it, a rule like "अलोऽन्त्यस्य" (1.1.52, "of the last sound") does not say replace anything — it is 1.1.49 that supplies "in place of."
The LSK never states it. Not late, not in a different chapter — absent from its 1,269, and from मध्यसिद्धान्तकौमुदी and सारसिद्धान्तकौमुदी too. Five sūtras the LSK does include still inherit "षष्ठी" and "स्थाने" from it by अनुवृत्ति:
Position 20 of the LSK's own walk — the strip below is steps 14 to 29, in the order the LSK actually presents them. The one outlined in red is अलोऽन्त्यस्य, silently leaning on a rule two chapters away in Pāṇini's text that this route never states.